Published on 18-May-2024

X-Ray Diffraction Primer: How Does XRD Work?

X-Ray Diffraction Primer: How Does XRD Work?

X-ray diffraction, or XRD for short, is an analytical technique that provides information about the structure and phase ID of crystalline materials. XRD can be used to identify single crystals and reveal their structure. Geologists find XRD particularly useful since it can be used to identify crystals present in a mixture, such as minerals in a rock. For minerals with variable formulas and structures, such as clays, XRD is the best method for identifying them and determining their proportion within a sample.

But how does XRD work? This blog post will dig into the science behind XRD and explain how it works in our field-portable XRD analyzers.

Science Behind X-Ray Diffraction (XRD)

The angle between the incoming and outgoing beam directions is called 2θ (2-theta)

During XRD analysis, a beam of X-rays is directed toward a sample, and the scattered intensity is measured as a function of the outgoing direction. By convention, the angle between the incoming and outgoing beam directions is called 2θ, or 2-theta.

For the simplest possible sample, consisting of sheets of charge separated by a distance d, constructive interference (greater scattered intensity) is observed when Bragg's Law is satisfied: n λ = 2 d sin θ.

XRD Technology in Practice

The BTX™ III benchtop XRD analyzer (left) and the TERRA™ II portable XRD analyzer (right) provide the power of large, complex laboratory systems in compact, lightweight designs

XRD instruments like our next-generation TERRA™ II and BTX™ III XRD analyzers use this technology to provide fast, reliable mineralogy and phase analysis of major and minor components in real-time directly on the analyzer.

Olympus XRD diffractometers also use a unique method to rapidly and easily collect and process XRD data, which enables us to make our XRD analyzers exceptionally compact and portable. Keep reading to learn more about our technique.

How does Olympus XRD Work?

Conventional goniometer-based XRD instruments use a reflection geometry technique to process XRD data. As a result, the instruments are large, have many moving parts, and often require external cooling. Another drawback is that they require a large batch of samples for analysis. In the past, these limitations meant that XRD analysis always took place in a lab. Our engineers moved XRD forward with a unique transmission geometry method where the X-ray beam passes through the sample.

This method requires no moving parts, enabling us to engineer the world's first commercial battery-operated, portable XRD (the successor is our new TERRA™ II instrument). Today, our XRD instruments continue to provide portability and ease of use, only requiring 15 mg of sample for analysis.

Once the sample is enclosed in the sample chamber, our XRD analyzers use a particle randomization method called powder liquefaction. With this method, our analyzers apply the constant piezo-induced frequency to the sample, which causes the powder to convect from top to bottom and rotate on its axis.

Within 30 seconds, every particle in the sample window will have passed through the X-ray beam in every possible orientation. As a result, our XRD instruments achieve 100% randomization - the most critical component of precise and accurate X-ray diffraction.

How to Achieve Quantitative Mineralogy Quickly and Easily?

We made the XRD process as simple as possible so our customers can achieve quantitative mineralogy results quickly and easily. The process can be explained in just a few steps:

1. Prep your sample. You can learn more about the easy sample prep steps in our blog post, Your Quick Guide to Fast Quantitative XRD Analysis

2. Start your test, and the analyzer passes X-rays through the convecting sample in the window.

3. X-rays hit the sample and diffract at a range of 2-theta angles.

4. The CCD detector measures diffraction.

5. SwiftMin® automated phase ID and quantitative software shows the phase or mineral ID in real-time directly onboard the analyzer or in the intuitive user interface